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Knölker complex
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| Names | |
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| IUPAC name
Dicarbonylhydro[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-2-hydroxy-1,3-bis(trimethylsilyl)-1H-inden-1-yl]iron | |
| Identifiers | |
3D model (JSmol) |
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| Properties | |
| C17H28FeO3Si2 | |
| Molar mass | 392.423 g·mol−1 |
| polar organic solvents | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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The Knölker complex is an organoiron compound, which is a catalyst for transfer hydrogenation.[1] The complex features an hydroxycyclopentadienyl ligand bound to an Fe(CO)2H centre. It is generated by the corresponding cyclopentadienone tricarbonyl by treatment with base followed by acidification.[2] It is named for Hans-Joachim Knölker The compound is related to the organoruthenium compound called Shvo's complex, a hydroxycyclopentadienyl derivative that also functions as a catalyst for hydrogenation.[3]
References
- ↑ Casey, Charles P.; Guan, Hairong (2007). "An Efficient and Chemoselective Iron Catalyst for the Hydrogenation of Ketones". Journal of the American Chemical Society. 129 (18): 5816–5817. Bibcode:2007JAChS.129.5816C. doi:10.1021/ja071159f. PMID 17439131.
- ↑ 3.0.CO;2-W"},"title":{"wt":"Demetalation of Tricarbonyl(cyclopentadienone)iron Complexes Initiated by a Ligand Exchange Reaction with NaOH—X-Ray Analysis of a Complex with Nearly Square-Planar Coordinated Sodium"},"year":{"wt":"1999"},"last1":{"wt":"Knölker"},"first1":{"wt":"Hans-Joachim"},"last2":{"wt":"Baum"},"first2":{"wt":"Elke"},"last3":{"wt":"Goesmann"},"first3":{"wt":"Helmut"},"last4":{"wt":"Klauss"},"first4":{"wt":"Rüdiger"},"journal":{"wt":"Angewandte Chemie International Edition"},"volume":{"wt":"38"},"issue":{"wt":"13–14"},"pages":{"wt":"2064–2066"},"pmid":{"wt":"34182704"}},"i":0}}]}' id="mwMQ"/>Knölker, Hans-Joachim; Baum, Elke; Goesmann, Helmut; Klauss, Rüdiger (1999). "Demetalation of Tricarbonyl(cyclopentadienone)iron Complexes Initiated by a Ligand Exchange Reaction with NaOH—X-Ray Analysis of a Complex with Nearly Square-Planar Coordinated Sodium". Angewandte Chemie International Edition. 38 (13–14): 2064–2066. doi:10.1002/(SICI)1521-3773(19990712)38:13/14<2064::AID-ANIE2064>3.0.CO;2-W. PMID 34182704.
- ↑ Bullock, R. Morris (2007). "An Iron Catalyst for Ketone Hydrogenations under Mild Conditions". Angewandte Chemie International Edition. 46 (39): 7360–7363. Bibcode:2007ACIE...46.7360B. doi:10.1002/anie.200703053. PMID 17847139.